Versatile 'nanocrystal gel' could enable advances in energy, defense and telecommunications
This graphic shows the materialin its gelled state (left) and its non-gelled state (right). When the materialis heated (right), the chemical bonds between the nanocrystals break and the gel breaks down. When the material is cooled (left), chemical bonds form between the nanocrystals and they organize themselves into a network (the gel).Molecular bonding(top)that controls gelation as a function of temperature is understood using supercomputer simulations (bottom). Credit: Kang, Valenzuela, et al./UT Austin

New applications in energy, defense and telecommunications could receive a boost after a team from The University of Texas at Austin created a new type of gel composed of tinycrystals each 10,000 times smaller than the width of a human.

The new material is easy to modify. Changing the temperature can switch it between two different states. The material can absorb different frequencies of light depending on whether it is in a gelled state or not. It could be used on the outside of buildings to control heating and cooling. This type of optical filter is used for thermal camouflage.

The gels can be tailored for different applications because of the designer components that connect them into networks. It's possible to modify the crystal structure to be useful for space craft or fiber-optic networks. gels can be switched based on ambient temperature or environmental toxins.

It could be useful if you could change the heat signature of an object.

This video shows the tunability of the material with temperature change. The sample starts off in its non-gelled state (labelled 'dispersion'). As the material is cooled, the material starts to transform into a nanocrystal gel (labelled 'Sol-to-gel transition'), until the entire sample is in gel form. Next, heat is applied, and the nanocrystal gel breaks down again. Credit: Cockrell School of Engineering, The University of Texas at Austin

The journal Science Advances published the new research.

The Center for Dynamics and Control of Materials is a National Science Foundation Materials Research Science and Engineering Center that brings together engineers and scientists from across campus to collaborate on materials science research.

The team was able to see the material change back and forth between its two states of gel and not-gel in the lab.

The Texas Advanced Computing Center at the University of Texas helped them understand what was happening in the gel when heat was applied. The simulations revealed the types of chemical bonds that hold thecrystals together in a network and how those bonds break when hit with heat.

This simulation shows 100nanocrystals at a temperature abovethe gelationthreshold. Here, mostof thenanocrystals remain in a free-flowing state without sticking to each other, called dispersion. Credit: Kang, Valenzuela, et al./UT Austin

This is the second unique gel created by this team, and they continue to pursue advances in this arena. A gel that can change between four states is currently being created by Kang. The gel would be made of two different types ofcrystals, each able to switch between states in response to chemical signals or temperature changes. Such gels are called "programmable" materials.

More information: Jiho Kang et al, Colorimetric quantification of linking in thermoreversible nanocrystal gel assemblies, Science Advances (2022). DOI: 10.1126/sciadv.abm7364. www.science.org/doi/10.1126/sciadv.abm7364 Journal information: Science Advances Citation: Versatile 'nanocrystal gel' could enable advances in energy, defense and telecommunications (2022, February 18) retrieved 18 February 2022 from https://phys.org/news/2022-02-versatile-nanocrystal-gel-enable-advances.html This document is subject to copyright. Apart from any fair dealing for the purpose of private study or research, no part may be reproduced without the written permission. The content is provided for information purposes only.