After scoring the winner, Deyverson was emotional.
Palmeiras beat Flamengo in extra time to retain their title in the Libertadores.
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The first World Cup final will take place in Montevideo, where Gabriel Barbosa scored in the second half to level the game.
It came after Raphael Veiga opened the scoring for Palmeiras.
The defending champion side-footed into the bottom corner.
David Luiz was denied by Weverton before Barbosa's leveller came.
Deyverson was able to run through after the poor touch from the Manchester United loanee allowed him to do so.
After the goal, Palmeiras had to hold on to the title and celebrate with their fans who had traveled from Sao Paolo.
