The foundation for complex life is provided by the oxygen rich atmosphere. Oxygen in the atmosphere is very reactive and can combine with other chemicals. Iron oxides and manganese oxides are found in the Earth. Scientists thought that the oxides were clues to the atmosphere on Mars.

That idea is put on hold by a new study.

“The link between manganese oxides and oxygen suffers from an array of fundamental geochemical problems.”

Jeffrey Catalano, McDonnell Centre for the Space Sciences, Washington University.

There are two craters containing oxides of manganese. We know this because of the two rovers. It was found that Mars had both surface water and oxygen in its atmosphere. A lot of liquid water and strong oxidizing conditions are needed to form these materials. "Here on Earth, we had lots of water, but no widespread deposits of manganese oxides until after the oxygen levels in our atmosphere rose." He was the lead author of a study on the minerals on Mars.

This is a HiRISE image of Opportunity Rover's path along the rim of Endeavour Crater. At Murray Ridge, the rover inadvertently overturned some rocks with its wheels. The rocks became targets of observation, and those observations showed the presence of manganese oxides. Image Credit: NASA/JPL/HiRISE.
This is a HiRISE image of Opportunity Rover’s path along the rim of Endeavour Crater. At Murray Ridge, the rover inadvertently overturned some rocks with its wheels. The rocks became targets of observation, and those observations showed the presence of manganese oxides. Image Credit: NASA/JPL/HiRISE.

According to a new study, atmospheric oxygen may not have been necessary for the formation of Martian oxides. There is a study about the formation of oxides on Mars. The first author is a graduate student at Washington University.

There are over 30 Manganese oxide minerals. They have been used by people for a long time. They may have been used to start fires by Neanderthals. They were used to make glass. They're used in metal ores, dry cell batteries, and as catalysts in hydrogen production.

This is one of the paintings in the Lascaux Caves in France, where paleolithic artists used manganese oxides and other materials to portray the large animals present at the time. Image Credit: By Prof saxx - Own work, Public Domain, https://commons.wikimedia.org/w/index.php?curid=2846254
This is one of the paintings in the Lascaux Caves in France, where paleolithic artists used manganese oxides and other materials to portray the large animals present at the time. Image Credit: By Prof saxx – Own work, Public Domain, https://commons.wikimedia.org/w/index.php?curid=2846254

They are widespread because of our planet's oxidizing atmosphere. They usually form at the interface between the hydroosphere and the atmosphere. The rovers used x-ray spectrometry to find the oxides in the rock.

The conditions that created them here on Earth must have existed on Mars. The findings were interesting because Mars' ancient habitability is something that holds our attention.

There is another pathway that doesn't require oxygen. The elements chlorine and bromine are 888-609- 888-609- 888-609- 888-609- 888-609-

The author is Jeffrey Catalano. At Washington University St. Louis, he is a professor of Earth and Planetary Sciences.

According to Catalano, the link between manganese oxides and oxygen suffers from an array of fundamental problems. According to Catalano, halogens occur on Mars in forms different from on the Earth and in much larger amounts.

Mars is rich in elements that are not found on Earth. The lead author of the book said that Mars has more chlorine and bromine concentrations than on Earth. chlorate and bromate are the main forms of both on Mars.

This image shows a chlorate ion (ClO3) and a bromate ion (BrO3). Could they have been the source of the oxygen that created manganese oxides on Mars? Image Credit: ChemSpider/Royal Society of Chemistry.
This image shows a chlorate ion (ClO3) and a bromate ion (BrO3). Could they have been the source of the oxygen that created manganese oxides on Mars? Image Credit: ChemSpider/Royal Society of Chemistry.

chlorate is an oxidizer. Is it possible that the oxygen needed to create the oxides was supplied by it? We have a precedent in the way we treat our water.

The reactions seen during chlorination of drinking water inspired us. It is necessary to apply knowledge from seemingly unrelated fields of science and engineering to understand other planets.

The lead author said that they treat the water before consuming it. One of the types of contaminants that can be found is Manganese.

Oxygenated chlorine and similar chemicals are used to decontaminate water. Chlorine can be a cause of concern. What can be done to make drinking water less polluted? Mitra said to use the metals. Chlorine has the same properties as bleach. The metal and oxygenated chlorine will react together to make products that can be removed from the environment.

There are important differences between Mars and Earth. It's tempting to assume that ancient Mars was also oxygen-rich because of the similarity in chemicals found on Earth and Mars.

The entire chemical environment on Mars is different than on other planets. Chemical reactions are not always about the chemicals themselves. In this case, the environment the reactions take place in was different than on Earth. The atmosphere of early Mars was likely CO2 rich. The pH of the water on Mars was dictated by CO2

This image shows the atmospheric composition of Mars and Earth (not to scale.) Mars' atmosphere is currently dominated by CO2, and this study shows it may never have had an oxygen-rich atmosphere like Earth. Image Credit: ESA
This image shows the atmospheric composition of Mars and Earth (not to scale.) Mars’ atmosphere is currently dominated by CO2, and this study shows it may never have had an oxygen-rich atmosphere like Earth. Image Credit: ESA

The researchers used both chlorate and bromate in the lab. The water on ancient Mars was moderately acidic with a pH between 3.5 and 6.5 due to the CO2 rich atmosphere.

When taking temperature, pressure, and pH into account, they found that the rover-observed manganese oxides could not have been produced by an oxygen rich atmosphere. Time scales decide it. The rovers found a very thick layer of the oxide. The experiment shows that if the atmosphere was oxygen rich, the layers would have been very thin.

The rate of oxidation by O2 is slower than by bromate. The low pH of Mars is important in this. The results show that bromate can oxidize Mn(ii) down to pH3 where oxidation by O2 becomes slower.

The experiments showed that bromate oxidizes manganese at a rate that can explain the findings of the rover. The authors wrote that chlorate produced no oxidation in the study.

A view from the Opportunity rover on Mars, which explored the rim of Endeavour Crater in 2014. Picture taken on Sol 3,798 in October 2014, while the rover was en route to a small crater called Ulysses. The rover's wheels overturned some rocks while traversing the rim of the crater, and those rocks contained manganese oxides. Credit: NASA/JPL-Caltech/Cornell Univ./Arizona State Univ.
A view from the Opportunity rover on Mars, which explored the rim of Endeavour Crater in 2014. Picture taken on Sol 3,798 in October 2014, while the rover was en route to a small crater called Ulysses. The rover’s wheels overturned some rocks while traversing the rim of the crater, and those rocks contained manganese oxides. Credit: NASA/JPL-Caltech/Cornell Univ./Arizona State Univ.

The oxide layers had to be thin if Oxygen were to produce the manganese oxide. The rovers found higher concentrations of manganese oxides than would be found in a nanometer range layer. There are substantial barriers to O2 having served as the oxidants that produced the deposits on Mars.

Since they aren't that thin, there had to be a different way of oxidation. Mars has a high concentration of bromate.

Oxygen does not have to be involved in oxidation. There are viable oxidants on Mars that can explain why the red planet is red. We didn't have a viable alternative to oxygen that could explain why manganese oxides were formed.

Mars is a puzzle we are only beginning to put together, and sometimes we overlook the differences between the two planets. It's tempting to think of Mars as a bad place to live. Mars might have had all of the above if something had gone wrong and the planet became barren.

There are a lot of differences between Earth and Mars. There are differences between Earth and Mars that affect the different aspects of the planets.

The study doesn't mean that life isn't possible on ancient Mars. Not all life forms need oxygen. Oxygen was not present in the atmosphere when life first appeared. Simple life forms that don't require it get by.

There are life forms that don't need oxygen. I don't think of it as a "setback to habitability", only that there was probably no oxygen-based life forms.

A type of lifeform called obligate anaerobes can't survive in the presence of low levels of Oxygen. Three new life forms that don't need oxygen were discovered in the Mediterranean in 2010. Under permanent anoxic conditions, they spend their entire lives. There are precedents for life on early Mars even if it lacks an atmosphere.

Meet Spinoloricus, the first described animal species that does not require oxygen at any point during its life. If Mars never had an oxygen-rich atmosphere, that doesn't necessarily rule out habitability. Image Credit: By Roberto Danovaro, Antonio Dell'Anno, Antonio Pusceddu, Cristina Gambi, Iben Heiner & Reinhardt Mobjerg Kristensen - Danovaro R., Dell'Anno A., Pusceddu A., Gambi C., Heiner I. & Kristensen R. M. (2010).
Meet Spinoloricus, the first described animal species that does not require oxygen at any point during its life. If Mars never had an oxygen-rich atmosphere, that doesn’t necessarily rule out habitability. Image Credit: By Roberto Danovaro, Antonio Dell’Anno, Antonio Pusceddu, Cristina Gambi, Iben Heiner & Reinhardt Mobjerg Kristensen – Danovaro R., Dell’Anno A., Pusceddu A., Gambi C., Heiner I. & Kristensen R. M. (2010).

The study won't be the last word on the planet. It is part of the puzzle. The samples the Perseverance rover is gathering in Jezero Crater are the most important pieces of the puzzle and will hopefully be in scientists' possession in about a decade or so.

There is limited information about the rocks and minerals on Mars. There was no mineralogical data from the rocks. Researchers deduced the mineralogy from the data given by the rovers.

Microanalysis data such as mineralogical could give more information. It is important to have samples from Mars to understand the chemical processes that took place on the surface in the past.

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