'Smart plastic' material is step forward toward soft, flexible robotics and electronics

Researchers at The University of Texas at Austin set out to create a plastic that is hard and rigid in some places and soft and stretchy in others, similar to life forms such as trees and shells. Their success has led to a new material that is 10 times tougher than natural rubber and could lead to more flexible electronics and robotics.

Today's findings are published in the journal Science.

"This is the first type of material that I've ever written about," said Page. It is possible to control crystallization and the physical properties of the material with the application of light.

Patterned sample is being stretched under uniaxial tension. Video was recorded with the sample between cross-polarizers, allowing for visualization of polymer chain alignment. The dark, opaque sections have been hardened. The transparent sections have been left soft and stretchy. Credit: The University of Texas at Austin

Synthetic materials have been used by scientists to mimic the properties of living structures. The flexibility and strength of living organisms can be combined with ease. Synthetic materials that mimic these attributes often fail, coming apart and ripping at the junctures between different materials.

When bringing materials together, they want to come apart. Page and his team were able to modify the structure of a plastic-like material using light.

Patterned island sample is being stretched and relaxed under uniaxial tension. Video was recorded with the sample as seen (left) and between cross-polarizers (right), allowing for visualization of polymer chain alignment. The dark, opaque spots are areas that have been hardened. Credit: The University of Texas at Austin

The building blocks for larger structures called polymers were formed with a small molecule that bind with others like it. After testing a dozen catalysts, they found one that resulted in a semicrystalline polymers similar to those found in existing synthetic rubber. There was a harder and more rigid material formed in the areas that the light touched.

The substance was stronger than most mixed materials because it was made of one material.

The catalyst is commercially available, the catalyst is commercially available, and the researchers used inexpensive blue LEDs as the light source in the experiment. It takes less than an hour to make the reaction and it is energy efficient and benign.

Patterned suture sample is being stretched under uniaxial tension. Video was recorded with the sample between cross-polarizers, allowing for visualization of polymer chain alignment. Credit: The University of Texas at Austin

The researchers will try to make more objects with the material.

Adrian Rylski, a PhD student at UT Austin, is one of the authors.

The material could be used to anchor electronic components in medical devices or Wearable Tech. Strong and flexible materials are desirable in a robot.

Patterned sample is being melted to show complete transparency and later the opacity returning as the sample cools and returns to a semicrystalline state. Credit: The University of Texas at Austin

The University of Texas at Austin and Henry L. Cater contributed to the research.

More information: Adrian K. Rylski et al, Polymeric multimaterials by photochemical patterning of crystallinity, Science (2022). DOI: 10.1126/science.add6975. www.science.org/doi/10.1126/science.add6975 Journal information: Science